Corrosion behaviour and mechanism of 6082 aluminium alloy in NaCl and Na2SO4 etchants

The corrosion behaviour of 6082 aluminium alloy was studied by measuring the electrochemical impedance spectra and electrode polarization curves. After the electrochemical tests, a microstructural analysis of the samples was conducted by using optical microscopy and electron scanning microscopy techniques to determine the corrosion mechanism. The results show that the Nyquist plot of the electrochemical impedance data in the NaCl solution consists of high- and low-frequency capacitive impedance loops. When ions are added to the NaCl etchant, the Nyquist plots of the electrochemical impedance data are composed of two different curves: a high-frequency capacitive impedance loop and a low-frequency inductive impedance loop. The corrosion current density increases with increasing concentration, and as a result, the corrosion resistance of the aluminium alloy decreases. The microstructures of 6082 aluminium alloy consist of Mg₂Si secondary particles in a large α-Al matrix. Pitting corrosion initially occurs at the boundary between the matrix and secondary particles because the electrode potentials of the matrix and secondary particles are different. Then, corrosion paths develop along the network-like grain boundaries, and finally, massive network-like corrosion occurs throughout the entire alloy.     

汽车涂装废水处理技术的研究进展

汽车涂装中产生大量的工业废水，主要包括脱脂废水、磷化废水、电泳废水和喷漆废水等,其典型污染物为重金属离子、表面活性剂、油漆颗粒、磷酸盐等，是一类复杂及难处理的高浓度工业废水。依据废水中所含污染物的不同，对涂装各工序废水进行分质预处理可有效地去除磷酸盐、重金属离子、悬浮固体、油类物质等污染物，有利于减轻后续生物或高级处理单元的负荷，提高整个处理系统的效率。本文综述近年来汽车涂装废水处理方面的研究成果或实践，旨在总结预处理工艺及主体处理工艺的优点及存在的不足，希望为汽车涂装废水处理达标排放及循环回用提供一些借鉴。     

LED灯丝灯胶的制备及其触变性

本文主要研究乙烯基苯基硅油、含氢苯基硅油、苯T树脂、催化剂、抑制剂等最优化配比,通过添加白炭黑等触变剂,使硅胶达到触变性流体,并对制成的LED灯丝灯硅胶进行触变性测试,当二氧化硅的用量为5%时,硅胶的触变性良好,屈服应力为49.0Pa,结构恢复时间为3.3s,满足灯丝灯的封装要求,为我国照明LED产业提供材料基础。     

微弧氧化Mg-3Al-1Zn镁合金应力腐蚀和腐蚀疲劳行为研究

本文主要对微弧氧化Mg-3Al-1Zn镁合金在空气和3.5 wt.%硫酸钠溶液两种环境下的应力腐蚀和腐蚀疲劳行为进行研究，并讨论其相互关系。微弧氧化处理后，Mg-3Al-1Zn镁合金的耐蚀性能得到明显改善。与Mg-3Al-1Zn镁合金基体相比，在空气中，微弧氧化后合金的应力腐蚀和腐蚀疲劳强度均下降了大约10 MPa。在3.5 wt.%硫酸钠溶液环境中，微弧氧化后合金的腐蚀疲劳性能仍然是恶化的，但是应力腐蚀强度却得到了显著改善，从58.24 MPa提高至202.08 MPa。这表明材料的力学性能（应力腐蚀和腐蚀疲劳）并不是与其腐蚀性能完全保持线性关系的。微弧氧化处理后镁合金在空气中的应力腐蚀断口为韧性断裂，在硫酸钠溶液环境中为解理断裂。而其腐蚀疲劳断口不论是在空气中还是在腐蚀环境中均为解理断裂。这主要是由于腐蚀环境和变换循环载荷的影响，两者共同作用将会加速裂纹扩展。这表明，周围环境和加载类型对材料断裂机理有重要影响。